Stresscorrosion cracking of steels in ammonia with. Although it has traditionally been termed stress corrosion cracking, crack growth has never been observed under a static loading condition. For example, titanium is fully resistant to corrosion and stress cracking in the national association of corrosion engineers nace test solution which consists of oxygenfree water containing about 3,000 ppm dissolved h 2 s, 5 percent nacl, and 0. Titanium, like any other metal, is subject to corrosion in some environments. Titanium resists general, crevice, and pitting corrosion and scc in all near neutral chloride brine up to a minimum of 8590oc. It has been found that low ph scc occurs in environments with a low concentration of. Effects of plastic deformations on the electrochemical and. Abstract the application of strainbased design for pipelines requires comprehensive understanding of the postyield mechanical behavior of materials. Although the mechanism of nearneutral ph scc is not as well understood as the. Nearneutral ph stress corrosion cracking susceptibility. Stress corrosion cracking of annealed and cold worked. Develop and validate the combined factor model introduced by chen and sutherby in 2007. Near neutral ph scc is more frequently found with coatings that shield cp current, such as michael baker jr.
National aeronaut ics and space admln istrat ion for sale by the clearinghouse for federal scientific and technical information. These soils were collected from pipeline sites where near neutral ph scc has been observed. The source of the co2 is typically the decay of organic matter and geochemical reactions in the soil. Effects of soil type of shanghai and electrode potential on. Corrosion resistant titanium the various grades of ati titanium exhibit differences in formability. Stress corrosion cracking, underground pipeline, pressure fluctuation, hydrostatic testing, nearneutral ph overview currently, there is a poor understanding of the effects of pressure related parameters operating pressure, pressure fluctuations, and hydrostatic testings on external stress corrosion crack propagation in pipelines in. Characteristics of nearneutralph stress corrosion cracks. At the same time, not studied the influence on resistance to scc of. The source of the co 2 is typically the decay of organic matter and geochemical reactions in the soil. The problem of stress corrosion cracking scc, which causes sudden failure of metals and other materials subjected to stress in corrosive environments, has a significant impact on a number of sectors including the oil and gas industries and nuclear power production.
The severity of four different soil environments toward the development of nearneutral ph stress corrosion cracking scc of pipeline steel was evaluated using slow strainrate testing ssrt. Assessment of stress corrosion cracking and hydrogen embrittlement. Pdf influence of plasticity on corrosion and stress. Corrosion performance of medical titanium alloy with. Delanty introduction the majority of instances of stress corrosion cracking scc in highpressure gas pipelines has been associated with the propagation of intergranular cracks.
Extensive field investigations have shown that nnphscc is characterized by wide transgranular cracks, and usually occurs in dilute nearneutral ph environments with a ph around 6. Cc technologies in 1992 to study the nearneutral ph scc phenomenon. Influence of strain rate on the stress corrosion cracking of x70 pipeline steel in dilute near neutral ph solutions b. They include carbon steel, stainless steel, copper, titanium, and nickelbased alloys, in mild, near neutral ph, reducing environment, sa lt environment, and alkaline environment. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. Titanium, alcohol, higher stress levels, lower water content. Despite decades of research, the mechanisms of near.
Stress corrosion cracking of x70 pipeline steel in near. Nearneutral ph stress corrosion cracking nonclassic type a nearneutral ph scc environment appears to be a dilute groundwater containing dissolved co2. These recommended practices represent an overview of the methods used by cepa member companies to. Chinese journal of biomedical engineering, 2006, 252. Chemical and physical mechanisms of salt stresscorrosion cracking in the titanium 811 alloyh. This research is aimed at understanding near neutral ph scc initiation under disbonded coatings of pipeline steels, and the effect of different environmental and operational factors on crack initiation. Ugia 215 discussion 229 the diffusion of corrosion products in hotsalt stresscorrosion crack ing of titanium r. The effects of soil type of shanghai and electrode potential from cathodic protection point on near neutral ph stress corrosion cracking scc behavior of pipeline steel x60 has been investigated for structural integrity assessment. Investigating a mechanism for transgranular stress. Managaing near neutral ph scc 3rd edition, may 2015 contents executive summary 1 glossary of terms 3 1. Bales langley research center langley station, hampton, va. Corrosion in sharp crevices in near neutral brine is possible with unalloyed titanium at about 200f 93c and above figure 2. Near neutral ph stress corrosion cracking of pipelines. Three components are required for stress corrosion cracking.
Stress corrosion cracking scc is defined as the growth of cracks due to the simultaneous action of a stress. Pdf initiation and propagation of nearneutral ph scc was. Commercial titanium can suffer intergranular stresscorrosion cracking see. Near neutral ph stress corrosion cracking nonclassic type a near neutral ph scc environment appears to be a dilute groundwater containing dissolved co 2. Stress corrosion cracking of pipelines begins with a brief introduction and then explores general principals of stress corrosion cracking, including two detailed case studies of pipeline failure. Stress corrosion cracking initiation under the disbonded. In this article, the impact of plastic prestrain on nearneutral ph stress corrosion cracking scc susceptibility of welded x70 steel was investigated with a slow strain rate tensile ssrt test. Intergranular stress corrosion cracking an overview. Theory and practice v s raja, tetsuo shoji the problem of stress corrosion cracking scc, which causes sudden failure of metals and other materials subjected to stress in corrosive environments, has a significant impact on a number of sectors including the oil and gas industries and nuclear power production. Nearneutral ph stress corrosion cracking nonclassic type a nearneutral ph scc environment appears to be a dilute groundwater containing dissolved co 2.
Stresscorrosioncracking characterization procedures and. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Scc crack propagation nearneutral ph solution does not occur under constant loading and fluctuation. Elgiloy 120 words exact match in snippet view article find links to article chemical composition, elgiloy is highly resistant to sulfide stress corrosion cracking and pitting, and can operate at temperatures up to 454c. Stress corrosion cracking on canadian oil and gas pipelinesscc scc scc scc scc scc scc.
In laboratory tests, nearneutral ph scc cannot in general be reproduced. The objective of the research described in this paper was to evaluate the influence of the composition of the sparging gas on the electrochemical corrosion kinetics, hydrogen permeation, and crack growth behavior of a line pipe steel in a simulated nearneutral ph cracking electrolyte. The original 1997 cepa stress corrosion cracking recommended practices hereafter referred to as the practices were prepared and made public by cepa in response to a the national energy board of canadas public inquiry mh295 into the problem of stress corrosion cracking scc in oil and gas pipelines. The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material. An overview of nearneutral ph stress corrosion cracking. It was found that there is a critical potential range, i. Chu 1 department of chemical and materials engineering, university of alberta, edmonton, alberta, canada t6g 2g6. Corrosion fatigue and nearneutral ph stress corrosion cracking of pipeline steel in very dilute carbonatebicarbonate with and without the presence of hydrogen sulfide using the. Ke assessment of stress corrosion cracking and hydrogen embrittlement susceptibility of buried pipeline steels a. Microstructure dependence of stress corrosion cracking. Influence of plasticity on corrosion and stress corrosion cracking behaviour in near neutral ph environment. Coating type and condition have the strongest effect on scc initiation and growth. Lowering the ph of the brine lowers the temperature at which crevice corrosion is likely, whereas raising the ph reduces crevice corrosion susceptibility. Bubenik, in trends in oil and gas corrosion research and technologies, 2017.
Environmentinduced cracking of materials 1st edition. Near neutralph scc is more frequently found with coatings that shield cp current, such as michael baker jr. The types of corrosion that have been observed on titanium may be classified under the general headings. Stress corrosion cracking an overview sciencedirect topics. Stress corrosion cracking is an insidious failure phenomenon that occurs in susceptible materials exposed to saltwater or corrosive substances in the presence of a sustained tensile stress. Grades with enhanced corrosion can extend this resistance to 300oc or more. Bahalaou, horeh, investigating the mechanism of stress corrosion cracking in nearneutral and high ph environments for api, 5l x52 steel, corros. Causes of stress corrosion cracking in pipelines ducorr. Exchanged effectively with related projects such as storage canister corrosion and cladding failure of spent nuclear fuel. Ops tto8 stress corrosion cracking study page 30 of 128 ops tto8 final draft. Scc in pipelines is a type of environmentally assisted cracking eac. Nearneutral ph stress corrosion cracking of pipelines. The slightly greater strengths of grades 2, 7 and 16 titanium are still quite formable, but less so than grades 1, 11 or 17.
Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. As defined in the nace standard rp02042004, stress corrosion cracking scc is the cracking of material produced by the combined action of corrosion and tensile stress residual or applied. Commercially pure titanium is generally resistant to stress corrosion cracking scc except in a few specific environments, such as aqueous halides 68, 69, nitrogen tetroxide n 2 o 4, anhydrous methanol, redfuming nitric acid, liquid or solid cadmium and liquid mercury. Mechanistic aspect of nearneutral ph stress corrosion. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. Ratio analysis diagram rad interpretive procedures have been evolved recently to provide generalized engineering solutions for fracture toughness assessments of structural titanium alloys. Grades 1, 11 and 17 titanium, which are the softest and most ductile grades, exhibit the greatest formability. Stress corrosion cracking international institute of. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. This paper investigates mechanistically stress corrosion cracking scc of an x70 pipeline steel that is under cathodic protection cp in a nearneutral ph solution. Tang x and cheng y 2011 quantitative characterization by microelectrochemical measurements of the synergism of hydrogen, stress and dissolution on nearneutral ph stress corrosion cracking of pipelines corros.
Delanty, transgranular stress corrosion cracking of high pressure pipelines in contact with solutions of near neutral ph, corrosion 50 1994 394408. Effects of plastic deformations on the electrochemical and stress. Cepa recommended practices for managaing nearneutral ph scc 1 of 158 3rd edition, may 2015 executive summary this 3rd stedition of the cepa recommended practices for stress corrosion cracking builds on the 1 and 2nd editions published in 1999 and 2007, respectively. The required tensile stresses may be in the form of directly applied stresses or in the form of residual. It is suggested that hydrogen induced cracking should dominate the scc at. Stress corrosion cracking scc of buried pipelines has been a recognized threat since 1965. Transgranular stress corrosion cracking of highpressure pipelines in contact with solutions of near neutral ph r. Mechanisms of highph and nearneutralph scc of underground. Stress corrosion cracking scc of pipeline steels in nearneutral ph environments has remained a significant integrity risk for oil and gas pipelines. In the case of near neutral ph scc, the cracking environment. Transgranular stress corrosion cracking of highpressure.
Stress corrosion cracking behaviour of api 5l x52 linepipe steel in nearneutral and high ph solution is mixcontrolled by anodic dissolution and hydrogen based mechanism. The earliest cracks to appear initiated at corrosion pits that formed around nonmetallic inclusions, and later cracks grew from corrosion p its that formed randomly on the surface. Pdf stress corrosion cracking of pipeline steel in nearneutral ph. No matter how well these pipelines are designed, constructed and protected, once in place they are subjected to environmental abuse, external damage, coating disbondments, inherent mill. Stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. Marine atmospheric scc of unsensitized stainless steel rock. The mechanism of scc changes with a change in applied cathodic potential, so that at low and high applied cathodic potentials, anodic dissolution and hydrogen embrittlement. Greg nelson doctoral candidate university of alberta. Although it has been demonstrated in laboratory tests that titanium alloys are susceptible to hot salt stress corrosion cracking, no service failures have ever been reported, even though titanium alloys have been used in. This investigation was aimed to understand the effect of minor cycles with very high r ratios minimum stress maximum stress on crack growth in air and in near. Stress corrosion cracking direct assessment sccda what is stress corrosion cracking. Scc guidelines for nearneutral ph scc earlystage crack. Development of guidelines for identification of scc sites.
Previous projects have focused on cracking in ns4, a simulated nearneutralph cracking. The effect on the corrosion resistance of titanium alloy in the artificial saliva with different ph valuej. Microstructure dependence of stress corrosion cracking initiation in x65 pipeline steel exposed to a nearneutral ph soil environment r. Newman department of chemical engineering and applied chemistry, university of toronto, canada. Cheng, mechanistic investigation of hydrogenenhanced anodic dissolution of x70 pipe steel and its implication on nearneutral ph scc. This form of cracking occurs in nearneutral ph 6 a research program was started at cc technologies laboratories, inc. Feb 11, 2002 for example, titanium is fully resistant to corrosion and stress cracking in the national association of corrosion engineers nace test solution which consists of oxygenfree water containing about 3,000 ppm dissolved h 2 s, 5 percent nacl, and 0. When alloyed with oxygen or aluminum, transgranular stress corrosion cracking can be induced in laboratory tests in seawater and. In the case of near neutralph scc, the cracking environment appears to. Titaniums corrosion resistance relies upon the formation of a very thin oxide film, which occurs spontaneously in air or water.
Mechanical and environmental effects on stress corrosion cracking scc susceptibility of x52 pipeline steel were investigated using slow strain rate tests ssrt performed in a glass autoclave. Chloride stress corrosion cracking in austenitic stainless steel. Commercial titanium can suffer intergranular stress corrosion cracking see stress corrosion cracking in methanolic environments and red fuming nitric acid but otherwise it is immune to failure. Effects of soil type of shanghai and electrode potential on near. Stress corrosion cracking of x70 pipeline steel in near neutral ph solution subjected to constant load and cyclic load testing. Failuresafe design also requires consideration of possible subcritical crack propagation slow fracture due to stress corrosion cracking scc. What causes stress corrosion cracking in pipelines.
Environmental aspects of nearneutral ph stress corrosion. Cepa recommended practices for managing near neutral ph. Stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment. Investigating the mechanism of stress corrosion cracking. Corrosion fatigue and nearneutral ph stress corrosion. The environment that causes near neutral ph scc has been established as a dilute bicarbonate environment and the effect of stress on this type of scc has received a considerable amount of research. Tensile specimens of titanium alloy grades 2,4,7 and 12 stressed. Nearneutral ph stress corrosion cracking nnphscc has been an integrity risk for oil and gas pipelines for more than two decades.